Maternity leave is 52 weeks max. However, you can request annual leave or parental leave (usually unpaid).
Mat leave is 52 weeks max but you can take a “career break” if offered by your employer, most likely unpaid. Info here https://www.gov.uk/career-breaks
I would speak to your HR department if possible. They should be able to tell you if you're able to take extended leave or a career break or similar
I think it depends on your workplace honestly, I used my holidays that accrued while I was off to extend mine